\$\begingroup\$ IF it is a 4S LiIon charger the battery is nominal 4x 3.6 = 14.4V BUT the charger will charge to a peak of 4.2 x 4 = 16.8V. SO follow it with a Constant voltage unit and it will charge to whatever CV you set. 13.7V is safe for floating a car battery, giving 2.4V headroom.
How to charge your battery: Set your battery charger based on your needs. Models vary, but most offer a “jumpstart” or “quick charge” mode for a speedy car battery charge, as well as a lower power, long-term charge mode designed to safeguard batteries and keep them in top shape.Charging a 12 Volt battery from a cigarette lighter is a simple process. You need the correct devices to feed the power from the socket into the target battery in usable form. Like any 12 Volt battery, you can charge a deep cycle battery in a variety of ways. The most common of these is to use a battery charger.
Connect the negative (-) cable to the negative terminal on the working battery. Connect the other end of the negative cable to a metal surface on the engine block or frame of the car with the dead battery. Start the vehicle with the working battery and let it run for a few minutes.a55X.